Onder andere met: Chris Evans (Steve Rogers / Captain America), Scarlett Johansson (Natasha Romanoff / Black Widow), Sebastian Stan (Bucky Barnes / Winter Soldier), Anthony Mackie (Sam Wilson / Falcon), Robert Redford (Alexander Pierce), Samuel L. Jackson (Nick Fury), Cobie Smulders (Maria Hill), Frank Grillo (Brock Rumlow), Maximiliano Hernández (Jasper Sitwell), Emily VanCamp (Kate / Agent 13), Hayley Atwell (Peggy Carter), Toby Jones (Dr. Arnim Zola), Callan Mulvey (Jack Rollins), Garry Shandling (Senator Stern)